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Acetochlor 50% EC: High-Efficacy Pre-Emergence Herbicide for Crop Protection

Acetochlor 50% EC (Emulsifiable Concentrate) is a premium selective herbicide formulated with 500 g/L of the active ingredient acetochlor, a chloroacetanilide compound renowned for its pre-emergence control of annual grassy and broadleaf weeds. This formulation combines solubility in organic solvents with emulsifying agents, enabling easy dilution in water for uniform soil application. Tradenames like Harness® and Warrant® often utilize similar EC formulations, trusted by growers worldwide for residual weed management in major row crops.

2. Technical Specifications

2.1 Chemical & Formulation Details

  • Active Ingredient: Acetochlor (CAS No. 34256-82-1)
  • Molecular Formula: C₁₄H₂₀ClNO₂
  • Formulation Type: 50% Emulsifiable Concentrate (500 g/L acetochlor)
  • Physical State: Light amber oily liquid
  • Solubility: 233 ppm in water; miscible in acetone, toluene
  • pH Range: 5.0–9.0 (stable in most agricultural waters)
  • Emulsion Stability: Passes 200x water dilution test with no phase separation

2.2 Mode of Action

  1. Selective Uptake: Absorbed by germinating weed roots and shoots (coleoptiles in grasses, hypocotyls in broadleaves).
  2. Biochemical Target: Inhibits fatty acid elongase (FAE), blocking very-long-chain fatty acid (VLCFA) synthesis.
  3. Impact on Weeds: Disrupts cell membrane formation, leading to meristematic tissue necrosis and stunted growth.
  4. Symptom Timeline: Chlorosis within 5–7 days, complete weed death in 14–21 days.

3. Application Guide for Key Crops

3.1 Target Crops & Dosages

Crop Weed Targets Dosage (L/ha) Application Timing
Corn Barnyardgrass, crabgrass 1.5–2.5 Pre-emergence (0–3 days post-planting)
Soybeans Pigweed, lambsquarters 1.0–2.7 Pre-emergence (soil OM <6%: 1.0–1.5 L; OM >6%: 1.5–2.7 L)
Peanuts Morningglory, spurge 1.7–3.0 Pre-emergence (North China); 1.0–1.25 L (South China)
Cotton Velvetleaf, crabgrass 1.0–1.5 Pre-emergence (cotyledon stage)

3.2 Application Best Practices

  • Water Volume: 200–400 L/ha for uniform soil coverage.
  • Adjuvants: Add non-ionic surfactant (0.25% v/v) to enhance soil adsorption.
  • Environmental Conditions: Apply at 15–25°C; require 10–20 mm rainfall/irrigation within 7 days to activate residual layer.
  • Tank Mixes:
    • Corn: Acetochlor 50% EC + atrazine (broadens spectrum)
    • Soybeans: Acetochlor 50% EC + sulfentrazone (improves broadleaf control)

4. Key Advantages of 50% EC Formulation

  1. Enhanced Solubility: Organic solvent base ensures quick mixing and uniform distribution.
  2. Residual Activity: 30–45 days of soil protection reduces herbicide application frequency.
  3. Cost Efficiency: Lower application rates (1–3 L/ha) compared to granular formulations.
  4. Crop Safety: Selective action in corn, soybeans, and peanuts due to metabolic detoxification.
  5. Resistance Management: Effective against glyphosate-resistant weeds when tank-mixed with Group 9 herbicides.

5. Safety & Regulatory Considerations

5.1 Toxicity & Environmental Impact

  • Mammalian Toxicity: Low acute toxicity (LD₅₀ > 2000 mg/kg for rats); wear PPE during application.
  • Aquatic Risk: Toxic to fish and algae (keep 100 m from water bodies); avoid runoff.
  • Soil Persistence: DT₅₀ 8–18 days (microbial degradation); minimal leaching in clay soils.

5.2 Rotational Crop Restrictions

Sensitive Crop Minimum Interval After Application
Wheat, barley 4 months (low rate) to 10 months (high rate)
Vegetables 12–18 months
Canola 12 months
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